AMMRL: reference for selective GHMBC

From: psandusk <psandusk_at_olemiss.edu>
Date: Mon, 11 Jun 2007 10:12:54 -0600

Dear AMMRL members,

Hello from Oxford, Mississippi, where it is pleasantly warm
and green.

Recently it's been suggested that I try a selective GHMBC in
order to achieve better resolution in the f1 dimension
(carbon domain). This would be an experiment using shaped
selective pulses on the carbon channel. Does anyone know of
a literature reference for this experiment?

I also have a question about proper terms to use in
describing HMBC spectra. As you know, for each carbon there
will be a line of peaks, degenerate in f1. Is there a proper
term used to describe this line of HMBC peaks originating on
one carbon? I have been using the term "skewer", but no one
seems to like that. Does anyone know the proper term?

As always, your help is greatly appreciated.

Very best to all.

Peter Sandusky

Peter Sandusky
Senior Research Scientist
National Center for Natural Products Research
University, Mississippi
Received on Mon Jun 11 2007 - 10:35:47 MST

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