Re: AMMRL: Chemical shifts of water at different temperatures.

From: Maxim Dubinnyi <dumkas_at_yandex.ru>
Date: Mon, 23 Jul 2018 12:32:54 +0300
NMR Chemical Shifts of Common Laboratory Solvents as Trace Impurities
Hugo E. Gottlieb, Vadim Kotlyar, and Abraham Nudelman
J. Org. Chem. 1997, 62, 7512-7515
https://pubs.acs.org/doi/abs/10.1021/jo971176v
 
% Temperature Dependence of HDO Chemical Shifts:
% δ = 5.060 - 0.0122T + (2.11 × 10-5 )T^2
% which reproduces the measured values to better than 1 ppb. For the 0 - 50o C range, the simpler
% δ = 5.051 - 0.0111T
% gives values correct to 10 ppb. For both equations, T is the temperature in °C.
 
Place the article above on your desktop :)
 
Maxim
 
21.07.2018, 22:53, "Zhang, Tracy Chunxin (GE Global Research, US)" <zhangc@ge.com>:

Dear all,


I wonder if any of you have a chart of the chemical shifts of water at different temperatures.  I remember seeing one, but am having a hard time finding it again.  Thank you!

 

Tracy Zhang

Analytical Chemist

GE Global Research

 

T +1 518 387 7642

F +1 518 387 6945

tracy.zhang@ge.com

www.ge.com

 

1 Research Circle

Niskayuna, NY 12309

 

GE imagination at work

 

 
 
-- 
С уважением,
Максим Дубинный
 
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Received on Sun Jul 22 2018 - 23:33:52 MST

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