Re: concentration standard 31P at pH 13-14

From: Peter Lundberg <peterl_at_raf.liu.se>
Date: Fri, 6 Dec 02 11:30:23 +0100

>I look for a stable compound at high pH values ( pH 13 - 14) for
>concentration standard 31P NMR spectroscopy. Indeed, I tried the
>Me3PO4. At acid pH this compound is actually stable, but at very
>basic pH the degradation is very fast.

Dear Eric,

I would like to recommend a (concentric) reference capillary with any
suitable compound, concentration and pH. This capillary can be
standardized against other concentration references if required. I guess
that it would work best with larger tubes like 10 mm or so.

73, Peter

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Received on Fri Dec 06 2002 - 09:55:36 MST

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