Re: [AMMRL] 99.8% MeOD vs 80% Ethylene Glycol

From: Clemens Anklin via groups.io <clemens.anklin=bruker.com_at_groups.io>
Date: Fri, 18 Aug 2023 19:25:53 +0000

Hi Weixing

if you do this on a cryoprobe this will be the expected result. 80% Glycol
gives a massive amount of radiation damping. This leads to different readings
as shown by Stefan Berger in https://doi.org/10.1002/mrc.1941

You can try to run a more accurate measurement by massively detuning the probe.

With best regards

Clemens


On 8/18/2023 3:09 PM, Walter Zhang wrote:


Dear All,
I need to use 80% Ethylene Glycol for high temperature calibration.

Before I do the calibration, I compared it with 99.8% MeOD at 303 K.

When I set temperature to 303 K,
99.8% MeOD gives 303.03 K while 80% Ethylene Glycol gives 300.57 K

The difference between the two calibration samples is 2.46 K.
Is this normal?
Your comments are appreciated!

Best regards,
Weixing Zhang
St. Jude Children’s Research Hospital
Memphis, TN 38105
USA


________________________________

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Clemens Anklin Ph.D. Vice President
Bruker BioSpin NMR Applications & Training
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Received on Fri Aug 18 2023 - 16:44:20 MST

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